Phase transitions under ultrahigh pressure.
نویسندگان
چکیده
منابع مشابه
Structural phase transitions in Bi2Se3 under high pressure
Raman spectroscopy and angle dispersive X-ray diffraction (XRD) experiments of bismuth selenide (Bi2Se3) have been carried out to pressures of 35.6 and 81.2 GPa, respectively, to explore its pressure-induced phase transformation. The experiments indicate that a progressive structural evolution occurs from an ambient rhombohedra phase (Space group (SG): R-3m) to monoclinic phase (SG: C2/m) and e...
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Using first-principles calculations we have studied the valence and structural transitions of the rare earth monotellurides RTe (R = Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm and Yb) under pressure. The self-interaction corrected local spin-density approximation is used to establish the ground state valence configuration as a function of volume for the RTe in both the NaCl (B1) and CsCl (B...
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Recent theoretical simulations using density functional theory (DFT) and novel low temperature high energy x-ray diffraction experiments clearly show the existence of a high pressure morphotropic phase boundary (MPB) in pure PbTiO(3). The experiments show a richer phase diagram than the simulations, with multiple monoclinic phases (Pm and Cm) in the MPB region. In this paper we examine the MPB ...
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Boron has a unique chemistry, responsible for remarkable complexities even in the pure element. I review some of the history of the discovery of this element, and recent surprises found in boron under pressure. I discuss the recent discovery of a new high-pressure phase, γ-B28, consisting of icosahedral B12 clusters and B2 pairs in a NaCl-type arrangement: (B2)(B12), and displaying a significan...
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ژورنال
عنوان ژورنال: Bulletin of the Japan Institute of Metals
سال: 1988
ISSN: 0021-4426,1884-5835
DOI: 10.2320/materia1962.27.967